Search results for "WATER INTERFACE"
showing 10 items of 23 documents
Unionid shells (Hyriopsis cumingii) record manganese cycling at the sediment-water interface in a shallow eutrophic lake in China (Lake Taihu)
2017
Abstract Aquatic eutrophication is becoming a serious environmental problem throughout the world. The utility of bivalves as bio-filters to improve water quality and reduce algal blooms has been widely acknowledged, but the potential usefulness of bivalve shells as retrospective monitors of eutrophication-induced environmental change has received little attention. Here, we present the first multi-year, high-resolution Mn/Ca shell records of the freshwater mussel, Hyriopsis cumingii (Lea, 1852) from a shallow eutrophic lake (Lake Taihu, China). Mn/Ca shell time-series of the two studied shells exhibit a high degree of synchrony after being placed in a precise temporal context by means of gro…
Behenic Acid as a Structural Model for Fatty Acid Monolayers at the Air/Water Interface: An X-Ray Diffraction Study
1992
We present an X-ray diffraction study of behenic (docosanoic) acid films at the air/water interface. Analysis of the rod profiles parallel and perpendicular to the surface provides detailed information on the unit cells of five different phases.
Experimental studies on the detachment of multi-walled carbon nanotubes by a mobile liquid interface
2017
International audience; Retention and detachment of colloidal particles from surfaces is often considered only in terms of spontaneous chemical dispersion when the surface is already fully submerged. Nevertheless, interfacial processes, where the particles are caught on a mobile liquid contact line by capillary effects are ubiquitous. Theoretical description of such interfacial processes exist for spherical microcolloids, while for anisotropic shapes the literature is limited. Arc-discharge synthesized multiwalled carbon nanotube (MWNT) material contains besides the very anisotropic tubes also irregular amorphous carbon particles (ACP) that both are strongly hydrophobic. As a water–air–soli…
Surface-Specific Spectroscopy of Water at a Potentiostatically Controlled Supported Graphene Monolayer
2019
Knowledge of the structure of interfacial water molecules at electrified solid materials is the first step toward a better understanding of important processes at such surfaces, in, e.g., electrochemistry, atmospheric chemistry, and membrane biophysics. As graphene is an interesting material with multiple potential applications such as in transistors or sensors, we specifically investigate the graphene–water interface. We use sum-frequency generation spectroscopy to investigate the pH- and potential-dependence of the interfacial water structure in contact with a chemical vapor deposited (CVD) grown graphene surface. Our results show that the SFG signal from the interfacial water molecules a…
Polyelectrolyte Brushes Grafted at the Air/Water Interface
1997
A new approach for the study of grafted polyelectrolytes is investigated: monolayers at the air/water interface of block copolymers consisting of a liquid hydrophobic and a polyelectrolyte block. ...
Influence of pH and temperature on the early stage of mica alteration
2012
Mineral dissolution and precipitation reactions actively participate in controlling fluid chemistry during water–rock interaction. In this study, the changes in the biotite and muscovite basal surface nano-morphology were evaluated during interaction with fluids of different pH (pH = 1.1, 3.3 and 5.7) at different temperatures (T =2 5, 120, and 200 C). Results show that at the nanometre scale resolution of the atomic force microscope (AFM), dissolution generates etch pits with a stair-shaped pattern over the (0 0 1) surface. The flux of dissolved elements decreases when pH increases. However, at pH 5.7, a change was found in the flux after 42 h of reaction when abundant gibbsite and kaolini…
Phospholipid and phospholipid-protein monolayers at the air/water interface.
1990
Effect of apolar phase dielectric constant on interfacial properties of β-lactoglobulin (dielectric constant and interfacial properties of β-lactoglo…
2005
International audience; In this work, we hypothesized that the difference in the dielectric constant value existing between two non-miscible phases such as oil and water could be partially responsible for both protein unfolding and reorganization of the protein structure at the interface. So, we replaced the oil phase, whose dielectric constant value is 2, by organic solvents chosen for both their non-miscibility with water and their range of dielectric constant values higher (range 6.1-7.2) than that of oil. Using a dynamic drop tensiometer, we studied both surface activity and viscoelastic properties of the milk protein at various interfaces. The aqueous phase (pH7; 25°C) contained the co…
Ellipsometric study of the physical states of phosphatidylcholines at the air-water interface
1990
Etude des couches monomoleculaires de dimyristoylphosphatidylcholine, de dipalmitoylphosphatidylcholine, de distearoyl phosphatidylcholine, de diarachidoylphosphatidylcholine a l'interface air/eau
Spectroscopic studies of the stability of monolayers of 2-docosylamino-5-nitropyridine at the air/water interface
1991
Monolayers of 2-docosylamino-5-nitropyridine (DCANP) at the air/water interface were investigated by UV/Vis spectroscopy. The combination of this method with the classic constant-area relaxation technique yields insight into the longtime stability and the collapse behavior of monolayers. We have demonstrated that monolayers of DCANP are certainly stable under standard deposition conditions. At surface pressures above 20 mN/m monolayer instabilities lead to the formation of a three-dimensional head-to-head multilayered structure.